TEST PAPER – SOLUTION-
SOLUTIONS-XII TOTAL MARKS 56
Q1. A sample of water is distilled at 2 atm pressure. Its b.p.
a)
1000C
b)
2000C
c)
2730C
d)
100 K
Q2. Equimolecular mixture will have same B.P. provided that they do
not undergo
a)
Dimerisation
b)
Association
c)
Dissociation
d)
All of above
Q3. The value of van’t Hoff factor for K4[Fe(CN)6]
is
a)
3
b)
2
c)
4
d)
5
Q4. The freezing point of 0.05 m solution of non-electrolyte in
water is
a)
– 1.860C
b)
– 0.930C
c)
– 0.0930C
d)
0.930C
Q5. The weight of urea dissolved in 100 mL of solution which
produces an osmotic pressure of 20.4 atm at 250C will be
a)
3 g
b)
4 g
c)
5 g
d)
6 g
Q6. The aqueous solution having osmotic pressure nearest to that of
equimolecular solution of K4[Fe(CN)6] is
a)
BaCI2
b)
Na2S04
c)
AI2(S04)3
d)
C12H22011
Q7. A mixture of ethanol and propanol has a vapour pressure of 290
mm at 270C. if mole fraction of ethanol is 0.65. Then what will be
the vapour pressure if vapour pressure of pure ethanol is 210 mm?
a)
333.1 mm
b)
441.5 mm
c)
890.2 mm
d)
None
Q8. For an aqueous solution of K4[Fe(CN)6] the
observed molecular weight of K4[Fe(CN)6] is
a)
73.6
b)
368
c)
76.3
d)
36.8
Q9. The ratio of the value of any colligative property for K4[Fe
(CN)6] solution to that of K4[Fe(CN)6]3
is
a)
1.0
b)
0.71
c)
1.4
d)
1.5
Q10. Azeotropic mixtures are
a)
Mixture of two solids
b)
Those which boil at different
temperature
c)
Constant boiling mixtures
d)
Immiscible liquids
Q11. Azeotropic mixtures of H20 and HCI boils at 108.50C.
By distilling the Azeotropic mixtures, it is possible to get
a)
Pure water
b)
Pure HCI
c)
Pure water and HCI
d)
Neither water nor HCI in their
pure state.
Q12. The value observed and calculated molecular weight of Ca(N03)2
are 65.4 and 164 respectively. The degree of dissociation of Ca(N03)2
is
a)
80%
b)
67.5%
c)
50%
d)
25%
Q13. At the same temperature, which of the following pairs of the
solutions would be isotonic?
a)
0.1M NaCI and 0.1M Na2S04
b)
0.1M Na2S04 and 0.1M Ca(N03)2
c)
0.1M NaCI and
0.1M urea
d)
0.1M urea and 0.2M MgCI2
Q14. Which of the following statement are correct?
a)
For ideal solution and
non-electrolytes, i = 1
b)
For electrolytes undergoing
association , i < 1
c)
For electrolytes undergoing
dissociation , i > 1
d)
All are correct
All
questions are compulsory
Negative marks
applicable
Each question
carries 4 Marks
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